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In the presence of platinum catalyst, hydrocarbon A adds hydrogen to form n-hexane. When hydrogen bromide is added to A instead of hydrogen, only a single bromo compound is formed. Which of the following is A?

 
CH3 –– CH2 –– CH = CH –– CH2 –– CH3
CH3 –– CH2 –– CH2 –– CH = CH –– CH3
CH3 –– CH = CH –– CH2 –– CH2 –– CH3
CH2 = CH –– CH2 –– CH2 –– CH2 –– CH3

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Why cannot the answer be option 4?